|
|
3-carboxy-10-(methylsulfanyl)-2-oxodecanoate + H+ <=> 2-Oxo-10-methylthiodecanoate + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18201
|
|
|
|
2-[(7''-methylsulfanyl)heptyl]malate <=> 2-[(2''-methylsulfanyl)heptyl]maleate + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18192
|
|
|
|
3-carboxy-7-(methylsulfanyl)-2-oxoheptanoate + H+ <=> 7-methylthio-2-oxoheptanoate + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18207
|
|
|
|
7-methylthio-2-oxoheptanoate + proteinogenic_amino_acid <=> L-trihomomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
MetaCyc:
RXNQT-4346
|
|
|
|
3-carboxy-9-(methylsulfanyl)-2-oxononanoate + H+ <=> 9-methylthio-2-oxononanoate + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18203
|
|
|
|
6-methylthio-2-oxohexanoate + acetyl-CoA + H2O <=> H+ + 2-[(4''-methylsulfanyl)butyl]malate + CoA
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438966
KEGG:
R08627
MetaCyc:
RXNQT-4166
|
|
|
|
2-[(2''-methylsulfanyl)hexyl]maleate + H2O <=> 3-[(6''-methylsulfanyl)hexyl]malate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18191
|
|
|
|
2-[(5''-methylsulfanyl)pentyl]malate <=> 2-[(2''-methylsulfanyl)pentyl]maleate + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18188
|
|
|
|
9-methylthio-2-oxononanoate + proteinogenic_amino_acid <=> L-pentahomomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
MetaCyc:
RXNQT-4348
|
|
|
|
2-[(3''-methylsulfanyl)propyl]malate <=> 2-[(2''-methylsulfanyl)propyl]maleate + H2O
|
4.2.1.170
2-(omega-methylthio)alkylmalate dehydratase
|
–
|
| |
BRENDA:
BS438077
MetaCyc:
RXN-18184
|
|
|
|
3-[(4''-methylsulfanyl)butyl]malate + NAD+ <=> 3-carboxy-7-(methylsulfanyl)-2-oxoheptanoate + NADH + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18206
|
|
|
|
3-[(7''-methylsulfanyl)heptyl]malate + NAD+ <=> 3-carboxy-10-(methylsulfanyl)-2-oxodecanoate + NADH + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18200
|
|
|
|
2-[(2''-methylsulfanyl)pentyl]maleate + H2O <=> 3-[(5''-methylsulfanyl)pentyl]malate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18189
|
|
|
|
3-carboxy-8-(methylsulfanyl)-2-oxooctanoate + H+ <=> 8-methylthio-2-oxooctanoate + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18205
|
|
|
|
2-[(2''-methylsulfanyl)propyl]maleate + H2O <=> 3-[(3''-methylsulfanyl)propyl]malate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18185
|
|
|
|
2-[(2''-methylsulfanyl)butyl]maleate + H2O <=> 3-[(4''-methylsulfanyl)butyl]malate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18187
|
|
|
|
3-[(6''-methylsulfanyl)hexyl]malate + NAD+ <=> 3-carboxy-9-(methylsulfanyl)-2-oxononanoate + NADH + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18202
|
|
|
|
3-carboxy-6-(methylsulfanyl)-2-oxohexanoate + H+ <=> 6-methylthio-2-oxohexanoate + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18209
|
|
|
|
3-[(3''-methylsulfanyl)propyl]malate + NAD+ <=> 3-carboxy-6-(methylsulfanyl)-2-oxohexanoate + NADH + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18208
|
|
|
|
2-[(4''-methylsulfanyl)butyl]malate <=> 2-[(2''-methylsulfanyl)butyl]maleate + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18186
|
|
|
|
2-[(2''-methylsulfanyl)heptyl]maleate + H2O <=> 3-[(7''-methylsulfanyl)heptyl]malate
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18193
|
|
|
|
8-methylthio-2-oxooctanoate + acetyl-CoA + H2O <=> H+ + 2-[(6''-methylsulfanyl)hexyl]malate + CoA
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438979
KEGG:
R08640
MetaCyc:
RXNQT-4172
|
|
|
|
9-methylthio-2-oxononanoate + acetyl-CoA + H2O <=> H+ + 2-[(7''-methylsulfanyl)heptyl]malate + CoA
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438985
KEGG:
R08644
MetaCyc:
RXNQT-4175
|
|
|
|
7-methylthio-2-oxoheptanoate + acetyl-CoA + H2O <=> H+ + 2-[(5''-methylsulfanyl)pentyl]malate + CoA
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438972
KEGG:
R08631
MetaCyc:
RXNQT-4169
|
|
|
|
5-methylthio-2-oxopentanoate + acetyl-CoA + H2O <=> H+ + 2-[(3''-methylsulfanyl)propyl]malate + CoA
|
2.3.3.17
methylthioalkylmalate synthase
|
–
|
| |
BRENDA:
BS438895
KEGG:
R08623
MetaCyc:
RXNQT-4163
|
|
|
|
2-Oxo-10-methylthiodecanoate + proteinogenic_amino_acid <=> L-hexahomomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
MetaCyc:
RXNQT-4349
|
|
|
|
2-[(6''-methylsulfanyl)hexyl]malate <=> 2-[(2''-methylsulfanyl)hexyl]maleate + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18190
|
|
|
|
3-[(5''-methylsulfanyl)pentyl]malate + NAD+ <=> 3-carboxy-8-(methylsulfanyl)-2-oxooctanoate + NADH + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18204
|
|
|
|
8-methylthio-2-oxooctanoate + proteinogenic_amino_acid <=> L-tetrahomomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
MetaCyc:
RXNQT-4347
|
|
|
|
6-methylthio-2-oxohexanoate + proteinogenic_amino_acid <=> L-dihomomethionine + a_2-oxo_carboxylate
|
2.6.1
|
–
|
| |
MetaCyc:
RXNQT-4345
|
|
